
D-Glucal CAS 13265-84-4



Factory Supply D-Glucal CAS 13265-84-4 with Best Price
- Appearance: White powder
- Purity: 99. 0%min
- Stock: In stock
- Sample: Available
- Zhishang Chemical: D-Glucal Supplier & Manufacturer
D-Glucal for Sale
Basic Info of D-Glucal
Chemical Name: | D-Glucal |
Other Name: | (2R,3S,4R)-2-(hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol; Glucal; D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-; D-glucene; D-Glucose |
CAS: | 13265-84-4 |
EINECS: | 236-259-3 |
Type: | Food additives; Pharmaceutical raw materials; Sweetning agents; Sugars |
Molecular Formula: | C6H10O4 |
Molecular Weight: | 146.14 |
Melting point | 58-60 °C (lit.) |
Boiling point | 325.5±42.0 °C(Predicted) |
density | 1.414±0.06 g/cm3(Predicted) |
refractive index | -10 ° (C=2, H2O) |
storage temp. | 2-8°C |
solubility | Soluble in Methanol. |
pka | 12.79±0.60(Predicted) |
optical activity | [α]21/D 7°, c = 1.9 in H2O |
Sensitive | Moisture Sensitive |
Brand Name: | Zhishang Chemical |
Provide: | D-Glucal MSDS; D-Glucal COA |
What is D-Glucal?
Glucal is a sugar aldehyde formed from glucose. It is a chemical intermediate for the synthesis of different oligosaccharides.
Utilizing Ferrier rearrangement, glucal and its by-products can be exchanged various other chemically useful sugars.
D-glucal, additionally known as D-glucose, is a pharmaceutical intermediate, which can be prepared from pentaacetylglucose through a three-step reaction. D-glucal can be utilized to prepare fluoroglycosyl-modified paclitaxel compounds.
D-Glucal Uses
D-glucal is an important component of oligosaccharide solution and solid phase synthesis.
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If you want to buy d-glucal, pls contact us to get a free quote.
Preparation of D-Glucal
Compound 8 (pentaacetylglucose) (10 g, 25.6 mmol) was dissolved in dry dichloromethane (60 mL). Under ice bath conditions, a solution of hydrobromide acetic acid (33%, mass percent) (4.9 mL, 2.0 equiv.) was slowly added thereto. The reaction was carried out at room temperature for 6 hours.
After the detection reaction was completed, an ice solution of saturated sodium bicarbonate was added to the reaction system to quench the reaction, and the two-phase extraction with dichloromethane and water was used to obtain an oily compound 9 (10.1 g, yield 96%, mass percentage) Rf0.6 (PE/EA2/1), used directly in the next step.
Compound 9 (5 g, 12.16 mmol) was dissolved in acetone, and zinc powder (7.63 g, 9.6 equiv.) and saturated NaH2PO4 solution (30 mL) were added at room temperature. The reaction was carried out at room temperature for 12 hours.
After that, it was filtered, extracted with dichloromethane and saturated NaHCO3 solution, dried over anhydrous Na2SO4, and concentrated by rotary evaporation to obtain oily compound 10 (3.1 g, yield 94%, mass percentage), Rf0.3 (PE/EA5/1 ), used directly in the next step.
At room temperature, MeONa (158.75 mg, 2.94 mmol, 0.4 equiv.) was added to a methanol solution (15 mL) of compound 10 (2 g, 7.35 mmol), and the reaction was performed for 1.5 hours. After the reaction was completed, the pH was adjusted to 7.0 with H+ ion exchange resin, Filtration, rotary evaporation and concentration to obtain oily compound 11 (1 g, yield 93%, mass percentage), Rf 0.25 (DCM/MeOH 10/1), which was directly used in the next step.
D-Glucal Supplier and Manufacturer
As a d-glucal supplier and manufacturer with a strict standard product quality system certificate, Zhishang Chemical has long been providing the best d-glucal raw materials to customers all over the world.
Over the years, relying on professional team experience and customer-centric team concept to meet customer needs in a timely manner, our company enjoys a high reputation in the world. At present, our company has served more than 6,000 customers and has established long-term cooperative relations with customers from many countries.
If you have a demand for d-glucal and related products, please contact our service staff Zhishang Chemical – White directly, and we will provide you with high-quality products at the best price.
Pre-Sales Service
* Prompt reply and 24 hours online, professional team to provide the best price and high-quality product.
* Sample testing support.
* Every batch of products will be tested to ensure its quality.
* The packing also can be according to the customers` requirement.
* Any inquiries will be replied to within 24 hours.
* We provide a Commerical Invoices, Packing Lists, Bills of loading, COA, Health certificates, and Origin certificates. If your markets have any special requirements, let us know.
After-Sales Service
* The fact of logistics information monitoring.
* Any questions about the product can be consulted at any time.
* Product has any problem can return.
Do you accept sample order?
We will make samples before mass production, and after the sample is approved, we’ll begin mass production. Doing 100% inspection during production, then doing random inspection before packing.
What’s your MOQ?
Our MOQ is 1kg. But usually we accept less quantities, such as 100g on the condition that the sample charge is 100% paid.
Is there a discount?
The different quantity has different discount.
HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?
You can get free samples for some products, you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests, we will manufacture the products according to your requests.
Do you supply product report?
Yes. We’ll give you product analysis report before shipping.
1. ≤50kg, Express delivery recommended, usually called DDU service;
2. ≤500kg, Air shipping recommended, usually called FOB, CFR, or CIF service;
3. >500kg, sea shipping recommended, usually called FOB, CFR, or CIF service;
4. For high-value products, please select air shipping and express delivery for safe.
Quality Control of D-Glucal

