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Tri-O-acetyl-D-glucal CAS 2873-29-2

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  • Appearance: White powder
  • Assay: 99. 0%min
  • Stock: In stock
  • Sample: Available
  • Zhishang Chemical: Tri-O-acetyl-D-glucal Supplement
2873-29-2

Basic Info of Tri-O-acetyl-D-glucal

What is Tri-O-acetyl-D-glucal?

3,4,6-tri-o-acetyl-d-glucose, also known as 1,5-anhydro-2-deoxy-d-arabino-hex-1-enitol triacetate, is a cyclic enol ether (glycoaldehyde) D-glucose protected by acetate. 3,4,6-tri-o-acetyl-d-gluconaldehyde is a structural unit that can be used to synthesize a series of carbohydrates with gluconaldehyde double bonds, allowing the introduction of other functional groups. As olefins, sugar aldehydes can be electrophilically added through double bonds to introduce halogens and epoxides or used to produce deoxymonosaccharides. 3,4,6-tri-o-acetyl-d-glucoaldehyde can undergo Ferrier rearrangement with alcohol and Lewis acid to obtain 2,3-unsaturated product.

Tri-O-acetyl-D-glucal Uses

  • D-glucoaldehyde derivatives.
  • 3,4,6-tri-o-acetyl-d-glucoaldehyde is a component of solution and solid phase oligosaccharide synthesis.
  • Tri-o-acetyl-d-glucose was used to prepare d-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.

Reference

  1. Tri-O-acetyl-D-glucal – ChemicalBook
  2. Tri-O-acetyl-D-glucal – PubChem

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