4,4'-Methylenedianiline CAS 101-77-9
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Factory Supply 4,4'-Methylenedianiline CAS 101-77-9 with Best Price
- Appearance: White crystal
- Purity: 99. 0%min
- Stock: In stock
- Sample: Available
- Zhishang Chemical: 4,4′-Methylenedianiline Supplier & Manufacturer
4,4'-Methylenedianiline: The Complete Guide
- Item 1: Basic Info of 4,4'-Methylenedianiline
- Item 2: What is 4,4'-Methylenedianiline?
- Item 3: 4,4'-Methylenedianiline Uses
- Item 4: The Manager has Something to Say
- Item 5: Preparation of 4,4'-Methylenedianiline
- Item 6: Reference
- Item 7: Quality Control of 4,4'-Methylenedianiline
- Item 8: Hot Sale Products
- Item 9: Get 4,4'-Methylenedianiline Quotation
4,4'-Methylenedianiline for Sale
Basic Info of 4,4'-Methylenedianiline
Basic Info
Chemical Properties
Other Info
Basic Info
Chemical Name: | 4,4′-Methylenedianiline |
Other Name: | Methylenedianiline; Methylene diamine; Dianiline; Methylenediamine; 4,4′-Diaminodiphenylmethane; 4,4′- Methylene two aniline; 4,4 ‘- Methylene diphenylamine |
CAS: | 101-77-9 |
EINECS: | 202-974-4 |
Type: | Synthetic material intermediates; organic raw materials |
Molecular Formula: | C13H14N2 |
Molecular Weight: | 198.26 |
Chemical Properties
Melting point | 89-91 °C(lit.) |
Boiling point | 242 °C2 mm Hg(lit.) |
density | 1.15 |
refractive index | 1.5014 (estimate) |
Fp | 430 °F |
solubility | water: soluble |
form | neat |
pka | 5.32±0.25(Predicted) |
Water Solubility | Slightly soluble. <0.1 g/100 mL at 19 ºC |
Other Info
Brand Name: | Zhishang Chemical |
Provide: | 4,4′-Methylenedianiline MSDS; 4,4′-Methylenedianiline COA |
What is 4,4'-Methylenedianiline?
4,4′-Methylenedianiline is a light brown crystalline solid with a faint amine smell. Flammable in case of heat or open fire. When heated and decomposed, it will emit toxic aniline and nitrogen oxide (NOx) smoke. Dihydrochloride is a crystalline solid soluble in water.
4,4′-Methylenedianiline is mainly used for the production of 4,4-‘methylene two aniline diisocyanate and other polyisocyanates used in the production of polyurethane foam.
4,4'-Methylenedianiline Uses
- 4,4′-Methylenedianiline utilized as analytical reagents and additionally made use of in organic synthesis.
- 4,4′-Methylenedianiline is mainly made use of in rubber items such as tires, sidewalls, plies, inner tubes, sharing pipes, rubber pipes, as well as V-belts.
- Generally used in the manufacture of polymer products such as epoxy resin, polycarbonate, polysulfone resin, phenolic unsaturated resin, polyetherimide, etc. It can also be utilized in the manufacture of polyvinyl chloride warmth stabilizers, plasticizers, rubber anti-oxidants, farming fungicides, paints, UV absorbers.
- Manufacture of dyes, determination of tungsten and also sulfate, antioxidants and antioxidants for rubber.
- 4,4′- methylene 2 aniline is used to generate polyurethane foam and epoxy material. By altering the lotion energy transportation system, it might result in pulmonary high blood pressure (PAH) in rats. According to the U.S. Epa (EPA), ecological and also food pollutants, drinking water pollutant candidate list 3 (CCL 3) substances. Dyes and also metabolites, environmental testing.
- 4,4′-Methylenedianiline manufacturing of methylene diphenyl diisocyanate (MDI) for the manufacturing of polyurethane; Hardener for epoxy resin, anti-corrosion materials, published circuit parts, color intermediates, filament wound pipes and also cord finishes.
- 4,4′-Methylenedianiline as a chemical intermediate for creating isocyanate and also polyisocyanate, it is used to prepare polyurethane foam as well as spandex fiber. As curing representative for epoxy resin and polyurethane elastomer; Manufacturing of polyamide; For the decision of tungsten and also sulfate; Prep work of azo dyes; As a corrosion inhibitor.
The Manager has Something to Say
This is William, CEO of Zhishang Chemical Co., Ltd.
Welcome to visit our factory . As the top chemical manufacturer, we have been striving for product quality, innovation , R&D, and customer service for the past 7 years. In the next 10 years or even longer, we are committed to becoming the most reliable chemical supplier in the world , creating a well-known international brand trusted by customers, with the spirit of “one meter wide, ten thousand meters deep”, we continue to focus on product research and development, continue to focus on customer service, continue to improve the supply chain service system, to create a professional chemical supply service team, to achieve win-win long-term cooperation. Please feel free to contact us if you have any questions.
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- Phone: +86 176 5311 3209
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If you want to buy 4,4'-methylenedianiline, pls contact us to get a free quote.
Preparation of 4,4'-Methylenedianiline
Dissolve 93 g (1 mol) of aniline in 96% alcohol, and gradually add 120 g (1 mol) of 40% formaldehyde solution to the cooled solution under proper stirring. After adding the second part of aniline molecule, add 93 g (1 mol) of aniline and continue the reaction until the odor of formaldehyde disappears.
After the reaction, the mixture was refluxed for 2 hours. Then add 130 g (1 mol) of aniline hydrochloride and continue boiling for 12 hours. Distill to remove alcohol, make the residue alkaline with sodium hydroxide solution, and distill with superheated steam to remove excess aniline. Then, the residual oil composed of 4,4 ‘- diaminodiphenylmethane was purified by dilute hydrochloric acid solution and dilute alkali reprecipitation.
Reference
- 4,4′-Methylenedianiline – ChemicalBook
- 4,4′-Methylenedianiline – PubChem
4,4'-Methylenedianiline Supplier and Manufacturer
As a 4,4′-methylenedianiline supplier and manufacturer with a strict standard product quality system certificate, Zhishang Chemical has long been providing the best 4,4′-methylenedianiline raw materials to customers all over the world.
Over the years, relying on professional team experience and customer-centric team concept to meet customer needs in a timely manner, our company enjoys a high reputation in the world. At present, our company has served more than 6,000 customers and has established long-term cooperative relations with customers from many countries.
If you have a demand for 4,4′-methylenedianiline and related products, please contact our service staff Zhishang Chemical – White directly, and we will provide you with high-quality products at the best price.
Service
FAQ
Shipping
Service
Pre-Sales Service
* Prompt reply and 24 hours online, professional team to provide the best price and high-quality product.
* Sample testing support.
* Every batch of products will be tested to ensure its quality.
* The packing also can be according to the customers` requirement.
* Any inquiries will be replied to within 24 hours.
* We provide a Commerical Invoices, Packing Lists, Bills of loading, COA, Health certificates, and Origin certificates. If your markets have any special requirements, let us know.
After-Sales Service
* The fact of logistics information monitoring.
* Any questions about the product can be consulted at any time.
* Product has any problem can return.
FAQ
Do you accept sample order?
We will make samples before mass production, and after the sample is approved, we’ll begin mass production. Doing 100% inspection during production, then doing random inspection before packing.
What’s your MOQ?
Our MOQ is 1kg. But usually we accept less quantities, such as 100g on the condition that the sample charge is 100% paid.
Is there a discount?
The different quantity has different discount.
HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?
You can get free samples for some products, you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests, we will manufacture the products according to your requests.
Do you supply product report?
Yes. We’ll give you product analysis report before shipping.
Shipping
1. ≤50kg, Express delivery recommended, usually called DDU service;
2. ≤500kg, Air shipping recommended, usually called FOB, CFR, or CIF service;
3. >500kg, sea shipping recommended, usually called FOB, CFR, or CIF service;
4. For high-value products, please select air shipping and express delivery for safe.
Quality Control of 4,4'-Methylenedianiline
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